效果如图

导入组件和图标

import { Select } from 'antd'
import { ManOutlined, WomanOutlined } from '@ant-design/icons';
const { Option } = Select;

数据

let userListOption = [
  {
    value:1,
    label:"小明",
    avatar: "http://xxx.com/1.jpg",
    sex:"1"
  },
  {
    value:2,
    label:"小静",
    avatar: "http://xxx.com/2.jpg",
    sex:"0"
  },
]

组件代码（样式省略）

<Select
  placeholder="请选择用户"
  optionLabelProp='label' // 这个属性指定选中后显示的内容
>
  {userListOption.map((option) => (
    <Option key={option.value} value={option.value} label={option.label}>
      <img src={option.avatar} />
      <span>{option.label}</span>
      {option.sex === "1" ? <ManOutlined /> : <WomanOutlined />}
    </Option>
  ))}
</Select>